A. V. Nemtarev, V. F. Mironov, E. N. Varaksina, Yu. V. Nelyubina, M. Yu. Antipin, R. Z. Musin, A. I. Konovalov, “Pyridine and benzyltriethylammonium chloride ate-complexes of 2,2,2-trichlorobenzo[<i>d</i>]-1,3,2-dioxaphosphole in reactions with alk-1-ynes”, Mendeleev Commun., 2007, Volume 17, Issue 6,Pages <nobr>327

This article is cited in 7 papers

Pyridine and benzyltriethylammonium chloride ate-complexes of 2,2,2-trichlorobenzo[d]-1,3,2-dioxaphosphole in reactions with alk-1-ynes

A. V. Nemtarev^a, V. F. Mironov^a, E. N. Varaksina^a, Yu. V. Nelyubina^b, M. Yu. Antipin^b, R. Z. Musin^a, A. I. Konovalov^a

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The reactions of the pyridine and benzyltriethylammonium chloride ate-complexes of 2,2,2-trichlorobenzo[d]-1,3,2-dioxaphosphole with alk-1-ynes afford 4-alkyl-2,6-dichloro- and 4-alkyl-2,7-dichloro-2-oxobenzo[e]-1,2-oxaphosphorinines; preferable chlorination of the phenylene moiety at the 7-position occurs when the ate-complex of 2,2,2-trichlorobenzo[d]-1,3,2-dioxaphosphole and benzyltriethylammonium chloride is used.

Language: English

DOI: 10.1016/j.mencom.2007.11.009

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