N. K. Gusarova, N. A. Chernysheva, S. N. Arbuzova, M. V. Bogdanova, N. I. Ivanova, A. A. Kudryavtsev, B. A. Trofimov, “Thiol elimination from tris[2-(phenylthio)ethyl]phosphine oxide: a convenient route to trivinylphosphine oxide”, Mendeleev Commun., 2006, Volume 16, Issue 1,Page 31

This article is cited in 5 papers

Thiol elimination from tris[2-(phenylthio)ethyl]phosphine oxide: a convenient route to trivinylphosphine oxide

N. K. Gusarova, N. A. Chernysheva, S. N. Arbuzova, M. V. Bogdanova, N. I. Ivanova, A. A. Kudryavtsev, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: Tris[2-(phenylthio)ethyl]phosphine oxide reacts with sodium amide to afford trivinylphosphine oxide in a good yield. The reaction involves the generation of phosphoryl-stabilised carbanions, which further eliminate benzene thiolate anions.

Language: English

DOI: 10.1070/MC2006v016n01ABEH002248