M. H. Königsmann, E. Lork, I. L. Odinets, V. G. Nenajdenko, N. E. Shevchenko, G.-V. Röschenthaler, “α-Pentafluoroethylated amines: a new synthetic approach”, Mendeleev Commun., 2006, Volume 16, Issue 3,Pages <nobr>141

This article is cited in 5 papers

α-Pentafluoroethylated amines: a new synthetic approach

M. H. Königsmann^ab, E. Lork^b, I. L. Odinets^c, V. G. Nenajdenko^d, N. E. Shevchenko^d, G.-V. Röschenthaler^b

^a Laboratorium für Anorganische Chemie, Zürich, Switzerland
^b Institut für Anorganische und Physikalische Chemie, Universität Bremen, Bremen, Germany
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^d Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Pentafluoroethyllithium generated from pentafluoroethane and n-butyl lithium added to selected imines, which were activated using BF₃ etherate, furnished α-pentafluoroethylated amines and, unexpectedly, depending on the stoichiometry of the reactants, bis(pentafluoroethyl)fluoro-N-(isopropyl)diisopropyliminium borate, whose molecular structure was confirmed by X-ray diffraction.

Language: English

DOI: 10.1070/MC2006v016n03ABEH002348