V. I. Krasnov, A. S. Vinogradov, V. E. Platonov, “Preparation of organozinc compounds from 3-chloroheptafluorotoluene and zinc: the participation of C–F bonds”, Mendeleev Commun., 2006, Volume 16, Issue 3,Pages <nobr>168

This article is cited in 6 papers

Preparation of organozinc compounds from 3-chloroheptafluorotoluene and zinc: the participation of C–F bonds

V. I. Krasnov, A. S. Vinogradov, V. E. Platonov

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Organozinc compounds were obtained from 3-chloroheptafluorotoluene and Zn in DMF; the C–Cl bond is mainly involved in this reaction; the addition of SnCl₂ changes the main reaction course in the direction of the participation of the C–F bond (para to the CF₃ group).

Language: English

DOI: 10.1070/MC2006v016n03ABEH002266