S. V. Moiseev, V. M. Goncharov, G. V. Zatonsky, V. F. Cherstkov, N. V. Vasil'ev, “Synthesis and cycloaddition reactions of polyfluorinated imines”, Mendeleev Commun., 2006, Volume 16, Issue 3,Pages <nobr>184

This article is cited in 7 papers

Synthesis and cycloaddition reactions of polyfluorinated imines

S. V. Moiseev^a, V. M. Goncharov^a, G. V. Zatonsky^b, V. F. Cherstkov^c, N. V. Vasil'ev^a

^a Military Academy of Radiation, Chemical and Biological Defence, Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Imines 3–6 containing fluorinated N-substituents were prepared by reactions of fluorinated sulfinylamines 1, 2 with hexafluoro-acetone and ethyl trifluoropyruvate; trifluoromethylsulfonylimines 3, 5 exothermically reacted with dienes at –50 °C to form cycloaddition products 7, 9 and α-aminoalkylation products 8, 10.

Language: English

DOI: 10.1070/MC2006v016n03ABEH002296