V. A. Miluykov, A. V. Kataev, O. G. Sinyashin, P. Lönnecke, E. Hey-Hawkins, “Protonation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide: the first example of [2 + 2] cycloaddition reaction for phosphacyclopentadiene”, Mendeleev Commun., 2006, Volume 16, Issue 4,Pages <nobr>204

This article is cited in 9 papers

Protonation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide: the first example of [2 + 2] cycloaddition reaction for phosphacyclopentadiene

V. A. Miluykov^a, A. V. Kataev^a, O. G. Sinyashin^a, P. Lönnecke^b, E. Hey-Hawkins^b

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Institut für Anorganische Chemie, Universität Leipzig, Leipzig, Germany

Abstract: Protonation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide occurs with a [1,5]-proton shift and leads to rac-trans-1,2,6,7-tetraphosphatricyclo[5.3.0.0^2,6]-3,9-decadiene, the product of an unusual [2 + 2] cycloaddition reaction

Language: English

DOI: 10.1070/MC2006v016n04ABEH002365