P. A. Troshin, O. A. Troshina, S. M. Peregudova, E. I. Yudanova, A. G. Buyanovskaya, D. V. Konarev, A. S. Peregudov, A. N. Lapshin, R. N. Lyubovskaya, “Chemical and electrochemical reduction of the highly chlorinated fullerenes C<sub>60</sub>Cl<sub>24</sub> and C<sub>60</sub>Cl<sub>30</sub>”, Mendeleev Commun., 2006, Volume 16, Issue 4,Pages <nobr>206–208</nobr>

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Mendeleev Commun., 2006 Volume 16, Issue 4, Pages 206–208 (Mi mendc3589)

This article is cited in 15 papers

Chemical and electrochemical reduction of the highly chlorinated fullerenes C₆₀Cl₂₄ and C₆₀Cl₃₀

P. A. Troshin^a, O. A. Troshina^a, S. M. Peregudova^b, E. I. Yudanova^a, A. G. Buyanovskaya^b, D. V. Konarev^a, A. S. Peregudov^b, A. N. Lapshin^a, R. N. Lyubovskaya^a

^a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Fully aromatic C₆₀Cl₃₀ is much more difficult to reduce than non-aromatic C₆₀Cl₂₄; the anion radicals C₆₀Cl_n⁻ (n = 24, 30) are unstable and undergo rapid decomposition with loss of Cl⁻ anions and partial substitution of chlorine atoms by organic groups.

Language: English

DOI: 10.1070/MC2006v016n04ABEH002346

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