O. V. Ryabtsova, A. F. Pozharskii, A. V. Degtyarev, V. A. Ozeryanskii, “Rearrangement of carbocations derived from 1,8-bis(dimethylamino)naphthyl-2-methanols into 4-R-1,1,3-trimethyl-2,3-dihydroperimidinium salts”, Mendeleev Commun., 2006, Volume 16, Issue 6,Pages <nobr>313

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Rearrangement of carbocations derived from 1,8-bis(dimethylamino)naphthyl-2-methanols into 4-R-1,1,3-trimethyl-2,3-dihydroperimidinium salts

O. V. Ryabtsova, A. F. Pozharskii, A. V. Degtyarev, V. A. Ozeryanskii

Department of Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation

Abstract: α-Phenylated 1,8-bis(dimethylamino)-2-naphthylmethyl carbocations have been shown to rearrange into 4-R-1,1,3-trimethyl-2,3-dihydroperimidinium cations through an intramolecular hydride shift from the 1-NMe₂ group.

Language: English

DOI: 10.1070/MC2006v016n06ABEH002399