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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2005 Volume 15, Issue 1, Pages 12–14 (Mi mendc3654)

This article is cited in 14 papers

Characterization of low-spin ferric hydroperoxo complexes with N,N’-dimethyl-N,N’-bis(2-pyridylmethyl)-1,2-diaminoethane

E. A. Duban, K. P. Bryliakov, E. P. Talsi

G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Hydroperoxo intermediates formed by the interaction of [FeII(BPMEN)(MeCN)2](ClO4)2 [BPMEN = N,N’-dimethyl-N,N’-bis-(2-pyridylmethyl)-1,2-diaminoethane] with H2O2 in a CH2Cl2–MeCN mixture were characterised using EPR spectroscopy.

Language: English

DOI: 10.1070/MC2005v015n01ABEH001981



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