A. Yu. Makarov, S. N. Kim, N. P. Gritsan, I. Yu. Bagryanskaya, Yu. V. Gatilov, A. V. Zibarev, “Interaction of 1,2,3-benzodithiazolyls (Herz radicals) with dioxygen”, Mendeleev Commun., 2005, Volume 15, Issue 1,Pages <nobr>14–17</nobr>

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Mendeleev Commun., 2005 Volume 15, Issue 1, Pages 14–17 (Mi mendc3655)

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Interaction of 1,2,3-benzodithiazolyls (Herz radicals) with dioxygen

A. Yu. Makarov^a, S. N. Kim^bc, N. P. Gritsan^cd, I. Yu. Bagryanskaya^a, Yu. V. Gatilov^a, A. V. Zibarev^ad

^a N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation
^c V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^d Department of Physics, Novosibirsk State University, Novosibirsk, Russian Federation

Abstract: The interaction of 4,6-di-tert-butyl-1,2,3-benzodithiazolyl (Herz radical) 1 with O₂ in a hydrocarbon solution leads to substituted N,N’-disulfinyl-2,2’-diaminodiphenyl disulfide 2, the radical decay kinetics corresponds to a self-termination reaction with a rate constant, which is a linear function of the concentration of dissolved O₂.

Language: English

DOI: 10.1070/MC2005v015n01ABEH001984

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