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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2023 Volume 33, Issue 2, Pages 259–260 (Mi mendc368)

This article is cited in 1 paper

Communications

Quasi-liquid composites based on poly(ethylene terephthalate) films with fullerene and dichlorobenzene

A. Yu. Yarysheva, L. M. Yarysheva, O. V. Arzhakova

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Quasi-liquid composites based on poly(ethylene terephthalate) (PET) films with 9 wt% solution of the C60 (70%) and C70 (∼30%) fullerenes mixture in dichlorobenzene (DCB) have been obtained. It has been shown that PET swelling in the fullerene solution in DCB is accompanied by penetration of fullerene into the polymer structure, and PET films are deformed by the mechanism of intercrystallite crazing. As has been revealed by UV spectroscopy, fullerene incorporated into composite remains monomeric as in solution.

Keywords: poly(ethylene terephthalate), composites, fullerene, polymer swelling, solvent-induced crystallization.

Language: English

DOI: 10.1016/j.mencom.2023.02.035



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