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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2005 Volume 15, Issue 3, Pages 98–99 (Mi mendc3695)

This article is cited in 7 papers

Methyl ent-16α-dichlorophosphitobeyeran-19-oate as the first example of phosphorylated diterpenoid derivatives of the beyerane series

V. L. Mamedova, K. A. Nikitina, V. E. Kataev, V. A. Alfonsov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The interaction of ent-16α-hydroxybeyeran-19-oate with PCl3 yielded methyl ent-16α-dichlorophosphitobeyeran-19-oate, whose hydrolysis resulted in methyl ent-16α-phosphitobeyeran-19-oate, a promising reagent for stereoselective synthesis and analysis.

Language: English

DOI: 10.1070/MC2005v015n03ABEH001990



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