M. A. Zolfigol, F. Shirini, I. Mohammadpoor-Baltork, A. G. Choghamarani, M. Hajjami, A. M. Sedaghat, “Silica chromate as an oxidising agent for the chemoselective oxidation of alcohols and the oxidative deprotection of trimethylsilyl ethers”, Mendeleev Commun., 2005, Volume 15, Issue 3,Pages <nobr>113

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Silica chromate as an oxidising agent for the chemoselective oxidation of alcohols and the oxidative deprotection of trimethylsilyl ethers

M. A. Zolfigol^a, F. Shirini^b, I. Mohammadpoor-Baltork^c, A. G. Choghamarani^a, M. Hajjami^a, A. M. Sedaghat^a

^a Department of Chemistry, School of Science, Bu Ali Sina University, Hamadan, Iran
^b Department of Chemistry, University of Guilan, Rasht, Iran
^c Department of Chemistry, College of Science, Isfahan University, Isfahan, Iran

Abstract: Silica chromate easily converts primary and secondary alcohols to corresponding carbonyl compounds in the presence of wet SiO₂ both in dichloromethane and under solvent-free conditions at room temperature with good to excellent yields. Primary and secondary trimethylsilyl ethers were converted into the corresponding carbonyl compounds or alcohols by using silica chromate and wet SiO₂ in dichloromethane at room temperature with good to excellent yields

Language: English

DOI: 10.1070/MC2005v015n03ABEH002005