X. Chen, L. Wang, J.-P. Guo, Sh.-P. Huang, D.-Sh. Liu, “Chain lithium complexes supported with β -diketiminate ligands containing pyridyl on the carbon framework”, Mendeleev Commun., 2005, Volume 15, Issue 4,Pages <nobr>160

This article is cited in 6 papers

Chain lithium complexes supported with β -diketiminate ligands containing pyridyl on the carbon framework

X. Chen, L. Wang, J.-P. Guo, Sh.-P. Huang, D.-Sh. Liu

School of Chemistry and Chemical Engineering and Institute of Modern Chemistry, Shanxi University, Shanxi, R.P. China

Abstract: The treatment of LiCH(SiMe₃)₂ with Bu^tCN followed by the addition of m- and p-cyanopyridines gave two tert-butyl- and pyridyl-substituted β-diketiminato lithium complexes [Li(L‾L′)n] [LL’ = N(SiMe₃)C(Bu^t)C(H)C(m-Py)NSiMe₃ (1) and LL’ = = N(SiMe₃)C(Bu^t)C(H)C(p-Py)NSiMe₃ (2)], and a one-dimensional polymeric chain could be observed in their crystal structures.

Language: English

DOI: 10.1070/MC2005v015n04ABEH002115