A. I. Vedernikov, N. A. Lobova, E. N. Ushakov, M. V. Alfimov, S. P. Gromov, “Diammonium cation-induced self-assembly into a pseudocyclic complex leading to the stereospecific [2 + 2]-photocycloaddition of a crown-containing bis(styryl) dye”, Mendeleev Commun., 2005, Volume 15, Issue 5,Pages <nobr>173

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Diammonium cation-induced self-assembly into a pseudocyclic complex leading to the stereospecific [2 + 2]-photocycloaddition of a crown-containing bis(styryl) dye

A. I. Vedernikov^a, N. A. Lobova^a, E. N. Ushakov^b, M. V. Alfimov^a, S. P. Gromov^a

^a Photochemistry Center, FSRC ‘Crystallography and Photonics’, Russian Academy of Sciences, Moscow, Russian Federation
^b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Abstract: A new bis(styryl) dye of the pyridine series containing two 18-crown-6 ether fragments forms a pseudocyclic complex with the 1,3-diammoniumpropane dication, which undergoes [2 + 2]-photocycloaddition affording a single cyclobutane isomer.

Language: English

DOI: 10.1070/MC2005v015n05ABEH002152