D. V. Vorobyeva, I. D. Titanyuk, I. P. Beletskaya, S. N. Osipov, “Synthesis of trifluoromethyl-containing depsipeptides <i>via</i> OH insertion of rhodium carbenoid into the carboxylic group of N-protected α-amino acids”, Mendeleev Commun., 2005, Volume 15, Issue 6,Pages <nobr>222

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Synthesis of trifluoromethyl-containing depsipeptides via OH insertion of rhodium carbenoid into the carboxylic group of N-protected α-amino acids

D. V. Vorobyeva^a, I. D. Titanyuk^b, I. P. Beletskaya^b, S. N. Osipov^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: A new approach to trifluoromethyl-depsipeptides involving the formation of a COO–CH(CF₃)CO link by a metal carbene insertion reaction into the COOH group of N-protected amino acids has been developed.

Language: English

DOI: 10.1070/MC2005v015n06ABEH002187