B. G. Zavin, N. V. Sergienko, E. V. Gorodnichev, V. D. Myakushev, A. A. Korlyukov, M. Yu. Antipin, “Rearrangement of the siloxane skeleton in Cu–Na-containing phenylsiloxanes”, Mendeleev Commun., 2005, Volume 15, Issue 6,Pages <nobr>245

This article is cited in 9 papers

Rearrangement of the siloxane skeleton in Cu–Na-containing phenylsiloxanes

B. G. Zavin^a, N. V. Sergienko^a, E. V. Gorodnichev^a, V. D. Myakushev^b, A. A. Korlyukov^a, M. Yu. Antipin^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The conversion of ‘sandwich’-like metalophenylsiloxane [PhSiO₂]₆Cu₄Na₄[PhSiO₂]₆ to ‘horse saddle’-like [PhSiO₂]₁₂Cu₄Na₄ was settled; this is the first example of chemical transformation of cage-like metalorganosiloxanes that occurs with rearrangement of Si–O–Si skeleton bonds and with the retaining of the cluster Cu₄Na₄.

Language: English

DOI: 10.1070/MC2005v015n06ABEH002191