B. A. Trofimov, A. G. Mal'kina, R. N. Kudyakova, O. A. Tarasova, V. V. Nosyreva, A. V. Afonin, “Catalytic methoxycarbonylation of alkoxyallenes”, Mendeleev Commun., 2004, Volume 14, Issue 2,Pages <nobr>61

This article is cited in 4 papers

Catalytic methoxycarbonylation of alkoxyallenes

B. A. Trofimov, A. G. Mal'kina, R. N. Kudyakova, O. A. Tarasova, V. V. Nosyreva, A. V. Afonin

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: Methoxyallene reacts with carbon monoxide in the PdCl₂–CuCl₂–NaHCO₃ (NaHCO₃/NaOAc) system in MeOH to afford methyl 2-(dimethoxymethyl)acrylate and 2-chloro-3,3-dimethoxyprop-1-ene; the third product, 2-chloro-1-methoxy-2-propenyl acetate, appears when NaHCO₃–NaOAc is used as a buffer component.

Language: English

DOI: 10.1070/MC2004v014n02ABEH001878