K. A. Lyssenko, V. A. Ponomarev, M. E. Gurskii, Yu. N. Bubnov, M. Yu. Antipin, “Intramolecular polarization of the dative B–O bond in the donor–acceptor complexes of 1-boraadamantanes with tetrahydrofuran”, Mendeleev Commun., 2004, Volume 14, Issue 5,Pages <nobr>189

This article is cited in 7 papers

Intramolecular polarization of the dative B–O bond in the donor–acceptor complexes of 1-boraadamantanes with tetrahydrofuran

K. A. Lyssenko^a, V. A. Ponomarev^b, M. E. Gurskii^b, Yu. N. Bubnov^a, M. Yu. Antipin^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The X-ray diffraction studies and B3LYP/6-311G^* calculations of the complexes of 1-boraadamantane and 4-bromo-1-boraadamantane with THF have revealed that the introduction of a halogen atom results in a shortening of the B−O bond due to intramolecular polarization.

Language: English

DOI: 10.1070/MC2004v014n05ABEH001920