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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2004 Volume 14, Issue 6, Pages 231–233 (Mi mendc3890)

This article is cited in 8 papers

Helix induction in an optically inactive poly[(4-carboxyphenyl)acetylene] film with chiral amines

K. Maeda, K. Hatanaka, E. Yashima

Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya, Japan

Abstract: An optically inactive cis-transoidal poly[(4-carboxyphenyl)acetylene] was found to form a predominantly one-handed helical conformation upon complexation with optically active amines and amino alcohols in the solid state, resulting in a characteristic induced circular dichroism in the polymer backbone region.

Language: English

DOI: 10.1070/MC2004v014n06ABEH002074



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