aInstitut für Organische Chemie, RWTH Aachen, Germany bOrganisch-Chemisches Institut, Universität Münster, Münster, Germany
Abstract:
An enantiomerically pure dinuclear triple-stranded titanium(IV) helicate is formed from a dicatechol diimine ligand with an (R,R)-1,2-diaminocyclohexane spacer and its stereochemical features are elucidated by experimental and theoretical methods.