aInstitut de Ciència de Materials de Barcelona, Consejo Superior de Investigaciones Científicas (CSIC), Bellaterra, Barcelona, Spain bInstituto de Ciència de Materiales de Aragön, Consejo Superior de Investigaciones Científicas (CSIC), Universidad de Zaragoza, Zaragoza, Spain
Abstract:
Diastereoselectivity in the polymerisation of isocyanides has been observed to be operating over approximately 2 nm, which separates the reactive group from the stereogenic centre, as revealed by circular dichroism spectroscopy.