M. Gruselle, R. Thouvenot, R. Caspar, K. Boubekeur, H. Amouri, M. Ivanov, K. Tõnsuaadu, “Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(V)] as a chiral counter-ion”, Mendeleev Commun., 2004, Volume 14, Issue 6,Pages 282

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Efficient resolution of the cis-[Ru(phen)₂(MeCN)₂]²⁺ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(V)] as a chiral counter-ion

M. Gruselle^a, R. Thouvenot^a, R. Caspar^a, K. Boubekeur^a, H. Amouri^a, M. Ivanov^b, K. Tõnsuaadu^c

^a Laboratoire de Chimie Inorganique et Matériaux Moléculaires, CNRS, Université Pierre et Marie Curie, Paris, France
^b Department of Chemistry, Russian State Pedagogical University, St. Petersburg, Russian Federation
^c Institute of Chemical Engineering, Tallinn Technical University, Tallinn, Estonia

Abstract: The synthesis of cis-Ru(phen)₂(MeCN)₂][(Δ)-tris(tetrachlorobenzenediolato)phosphate(V)]₂ abbreviated as [1]-[Δ-TRISPHAT]₂ and the separation of a mixture of the diastereomeric ion pairs by column chromatography are considered. The X-ray structure of [Δ-1][Δ-TRISPHAT]₂ is briefly described, as well as the CD curves of [Δ-1][Δ-TRISPHAT]₂ and [Δ-1][Δ-TRISPHAT]₂ fractions.

Language: English

DOI: 10.1070/MC2004v014n06ABEH002034