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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2004 Volume 14, Issue 6, Pages 293–295 (Mi mendc3916)

This article is cited in 14 papers

Kinetic resolution of 1-methyl- and 1-phenyl-3-amino-1,2-dicarba-closo-dodecaboranes via acylation with chiral acyl chlorides

G. L. Levita, V. P. Krasnova, A. M. Demina, M. I. Kodessa, L. Sh. Sadretdinovaa, T. V. Matveevaa, V. A. Ol'shevskayab, V. N. Kalininb, O. N. Chupakhina, V. N. Charushina

a I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A study of the kinetic resolution of racemic 1-substituted 3-amino-1,2-dicarba-closo-dodecaboranes by chiral acyl chlorides has shown that N-tosyl-(S)-prolyl and N-phthaloyl-(S)-alaninyl chlorides are more efficient resolving agents than (S)-naproxen chloride.

Language: English

DOI: 10.1070/MC2004v014n06ABEH002047



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