R. G. Kostyanovsky, V. Schurig, K. A. Lyssenko, O. Trapp, G. K. Kadorkina, V. R. Kostyanovsky, B. B. Averkiev, “Stereochemisty of 3,3-disubstituted 2-methoxy-1,2-oxazolidines”, Mendeleev Commun., 2004, Volume 14, Issue 6,Pages <nobr>306

This article is cited in 8 papers

Stereochemisty of 3,3-disubstituted 2-methoxy-1,2-oxazolidines

R. G. Kostyanovsky^a, V. Schurig^b, K. A. Lyssenko^c, O. Trapp^b, G. K. Kadorkina^a, V. R. Kostyanovsky^a, B. B. Averkiev^c

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b Institut fuer Organische Chemie, Eberhard Karls Universitaet Tuebingen, Tuebingen, Germany
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The conformations and anomeric effects for 1–3 in solution and for 3 in the solid state were investigated. The resolution of 1 by enantioselective gas chromatography was carried out and activation parameters of inversion in 1 were determined. The asymmetric transformation of the title compounds in an optically active solvent is discussed.

Language: English

DOI: 10.1070/MC2004v014n06ABEH002036