T. S. Dorosheva, K. P. Bryliakov, E. P. Talsi, “Multinuclear NMR-spectroscopic characterization of alkylperoxo complexes of molybdenum(VI)”, Mendeleev Commun., 2003, Volume 13, Issue 1,Pages <nobr>8

This article is cited in 2 papers

Multinuclear NMR-spectroscopic characterization of alkylperoxo complexes of molybdenum(VI)

T. S. Dorosheva^a, K. P. Bryliakov^b, E. P. Talsi^b

^a Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation
^b G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: An alkylperoxo molybdenum(VI) intermediate was identified in the reaction of Bu^tOOH with the 1,2-cyclohexanediolo complex of molybdenum(VI) in CHCl₃ using ¹³C, ¹⁷O and ⁹⁵Mo NMR spectroscopy.

Language: English

DOI: 10.1070/MC2003v013n01ABEH001636