W. A. Smit, A. V. Gromov, E. A. Yagodkin, “Adducts of ArSCl with vinyl ethers or esters as synthones in geminal alkylation”, Mendeleev Commun., 2003, Volume 13, Issue 1,Pages <nobr>21

This article is cited in 5 papers

Adducts of ArSCl with vinyl ethers or esters as synthones in geminal alkylation

W. A. Smit^a, A. V. Gromov^b, E. A. Yagodkin^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: The in situ-prepared adducts of arylsulfenyl chloride and vinyl ethers (esters) were employed as synthetic equivalents of 1,1-bis-electrophiles in the Lewis acid-promoted reaction sequence with two different carbon nucleophiles resulting in the formation of geminal bisalkylation products.

Language: English

DOI: 10.1070/MC2003v013n01ABEH001710