G. E. Salnikov, A. M. Genaev, V. I. Mamatyuk, “Unusually strong temperature dependence of <sup>13</sup>C chemical shifts and degenerate conformational exchange in cyclobutenyl carbocations”, Mendeleev Commun., 2003, Volume 13, Issue 2,Pages <nobr>48

This article is cited in 7 papers

Unusually strong temperature dependence of ¹³C chemical shifts and degenerate conformational exchange in cyclobutenyl carbocations

G. E. Salnikov, A. M. Genaev, V. I. Mamatyuk

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The unusually strong temperature dependence of ¹³C chemical shifts is observed in methyl-substituted cyclobutenyl carbocations because of a very low inversion barrier of a four-membered ring.

Language: English

DOI: 10.1070/MC2003v013n02ABEH001702