G. I. Sadrtdinova, D. A. Bardonov, K. A. Lyssenko, M. E. Minyaev, I. E. Nifant'ev, D. M. Roitershtein, “(Cyclopentadienyl)neodymium borohydrides with auxiliary N<sub>3</sub>-heterocyclic ligands”, Mendeleev Commun., 2023, Volume 33, Issue 3,Pages <nobr>357–359</nobr>

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Mendeleev Commun., 2023 Volume 33, Issue 3, Pages 357–359 (Mi mendc396)

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Communications

(Cyclopentadienyl)neodymium borohydrides with auxiliary N₃-heterocyclic ligands

G. I. Sadrtdinova^ab, D. A. Bardonov^abc, K. A. Lyssenko^d, M. E. Minyaev^ac, I. E. Nifant'ev^abe, D. M. Roitershtein^abc

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b National Research University Higher School of Economics (HSE University), Moscow, Russian Federation
^c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^d G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation
^e Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Mononuclear [CpNd(BH₄)₂L] borohydrides comprising L = 1,3,5-trimethyl-1,3,5-triazacyclohexane (Me₃tach) and L = 1,4,7-trimethyl-1,4,7-triazacyclononane (Me₃tacn) were obtained and structurally characterized. Their catalytic activity in coordination–insertion ring-opening poly-merization of ε-caprolactone was studied.

Keywords: lanthanide complexes, neodymium complexes, cyclopentadienyl, borohydrides, crystal structure, polymerization, ε-caprolactone..

Language: English

DOI: 10.1016/j.mencom.2023.04.019

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