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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2003 Volume 13, Issue 3, Pages 102–104 (Mi mendc3975)

This article is cited in 6 papers

Generation of an optically active rhodium(III) complex by crystallization-induced spontaneous resolution of a racemic mixture

I. L. Odinets, O. I. Artyushin, E. V. Sharova, E. I. Goryunov, D. G. Golovanov, K. A. Lyssenko, P. V. Petrovskii, T. A. Mastryukova

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Racemic (π-pentamethylcyclopentadienyl)(2,2,2-trifluoro-1-phenylethyl diethylphosphinite)rhodium dichloride 2 was found to be a conglomerate, which undergoes spontaneous resolution during crystallization.

Language: English

DOI: 10.1070/MC2003v013n03ABEH001778



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