A. D. Manin, D. V. Golubenko, P. A. Yurova, A. B. Yaroslavtsev, “Improvement of Li/Mg monovalent ion selectivity of cation-exchange membranes by incorporation of cerium or zirconium phosphate particles”, Mendeleev Commun., 2023, Volume 33, Issue 3,Pages <nobr>365

This article is cited in 5 papers

Communications

Improvement of Li/Mg monovalent ion selectivity of cation-exchange membranes by incorporation of cerium or zirconium phosphate particles

A. D. Manin^ab, D. V. Golubenko^a, P. A. Yurova^ab, A. B. Yaroslavtsev^ab

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b National Research University Higher School of Economics (HSE University), Moscow, Russian Federation

Abstract: To improve the selectivity of cation-exchange membranes to the transfer of lithium with respect to magnesium during the electrodialysis desalination of lithium and magnesium sulfates solutions, the surface of a commercial cation-exchange membrane based on sulfated polystyrene was modified with cerium(III, IV) and zirconium phosphates. Upon incorporation of phosphate particles, the Li/Mg selectivity coefficients of the membranes increased up to 113%.

Keywords: ion-exchange membranes, selectivity, modification, hybrid membranes, lithium, zirconium phosphate, cerium phosphate.

Language: English

DOI: 10.1016/j.mencom.2023.04.022

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