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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2003 Volume 13, Issue 4, Pages 175–177 (Mi mendc4011)

This article is cited in 15 papers

Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine

M. V. Lobanova, K. P. Bryliakov, E. A. Duban, E. P. Talsi

G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Quantitative data on the stability and reactivity of the peroxidic intermediates [FeIII(TPA)(OOH)L](ClO4)2 and [FeIII(TPA)-(OOBut)L](ClO4)2 [TPA = tris(2-pyridylmethyl)amine; L = MeCN, H2O, MeOH and Py] were obtained for the first time.

Language: English

DOI: 10.1070/MC2003v013n04ABEH001727



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