K. V. Shuvaev, V. A. Bagryansky, N. P. Gritsan, A. Yu. Makarov, Yu. N. Molin, A. V. Zibarev, “New polysulfur–nitrogen heterocycles as precursors of thiazyl radicals”, Mendeleev Commun., 2003, Volume 13, Issue 4,Pages <nobr>178–179</nobr>

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Mendeleev Commun., 2003 Volume 13, Issue 4, Pages 178–179 (Mi mendc4012)

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New polysulfur–nitrogen heterocycles as precursors of thiazyl radicals

K. V. Shuvaev^a, V. A. Bagryansky^b, N. P. Gritsan^b, A. Yu. Makarov^c, Yu. N. Molin^b, A. V. Zibarev^c

^a Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation
^b V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^c N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Both thermolysis and photolysis of 1,2,4λ⁴δ²,3,5- and 1,3λ⁴δ²,5,2,4-benzotrithiadiazepines in hydrocarbon solvents yielded stable 1,2,3- and 1,3,2-benzodithiazolyls, which can be considered as a particular case of a previously unmentioned trend of neutral polysulfur–nitrogen heterocycles to form thiazyl π-radicals.

Language: English

DOI: 10.1070/MC2003v013n04ABEH001741

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