Abstract:
The influence of the electrolyte nature and cation charge on the adsorption properties of cucurbit[6]uril supramolecular complexes are established and discussed. The results show the narrowing of the adsorption potential region of these complexes with increasing cation charge, and the possibility to form an adsorbate layer of supramolecular cations associated with surface-active electrolyte anions at the positive boundary of the adsorption potential region.