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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2003 Volume 13, Issue 6, Pages 252–253 (Mi mendc4049)

This article is cited in 2 papers

Metal–metal bond energy in a binuclear molybdenum(III) aqua complex

A. A. Proyavkin, I. A. Dementiev, A. O. Kozin, Yu. V. Kondratiev, D. V. Korol'kov

Department of Chemistry, St. Petersburg State University, St. Petersburg, Russian Federation

Abstract: The enthalpies of oxidation of mononuclear [Mo(H2O)6]3+ and binuclear [Mo2(μ-OH)2(H2O)8]4+ complexes in aqueous solutions were determined by calorimetric titration, and the metal–metal bond energy was estimated.

Language: English

DOI: 10.1070/MC2003v013n06ABEH001732



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