Yu. A. Azev, E. Lork, T. Duelcks, D. Gabel, “Unexpected reactivity of 3-ethylsulfonyl-1,2,4-triazines with B12H11SH⌉2–: first examples of the synthesis of boron-centered as-triazines and thioesters of ethyl sulfinic acid”, Mendeleev Commun., 2003, Volume 13, Issue 6,Pages 262

This article is cited in 2 papers

Unexpected reactivity of 3-ethylsulfonyl-1,2,4-triazines with B₁₂H₁₁SH⌉^2–: first examples of the synthesis of boron-centered as-triazines and thioesters of ethyl sulfinic acid

Yu. A. Azev^a, E. Lork^b, T. Duelcks^b, D. Gabel^b

^a Ural Scientific Research Institute of Technology of Medical Preparations, Ekaterinburg, Russian Federation
^b Department of Chemistry, University of Bremen, Bremen, Germany

Abstract: The reaction of 3-ethylsulfonyl-5-methylamino-6-methylcarboxamido-1,2,4-triazine 1 with B₁₂H₁₁SH⌉^2– yields the boron-containing derivatives of 1,2,4-triazine 3. The interaction of 5,7-dimethyl-5,6,7,8-tetrahydropyrimido[4,5-e][1,2,4]triazine-6,8-dione 2 with mercaptoborane B₁₂H₁₁SH⌉^2– gives boron-containing thiosulfinate 4 and bis(heteryl) ether 5.

Language: English

DOI: 10.1070/MC2003v013n06ABEH001843