A. A. Sobanov, A. N. Vedernikov, G. Dyker, B. N. Solomonov, “Synthesis and reactivity of extremely thermally stable trialkylpalladium(IV) complexes supported with 1,4,7-triazacyclononane”, Mendeleev Commun., 2002, Volume 12, Issue 1,Pages <nobr>14

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Synthesis and reactivity of extremely thermally stable trialkylpalladium(IV) complexes supported with 1,4,7-triazacyclononane

A. A. Sobanov^a, A. N. Vedernikov^a, G. Dyker^b, B. N. Solomonov^a

^a Department of Chemistry, V.I. Ul'yanov-Lenin Kazan State University, Kazan, Russian Federation
^b Gerhard-Mercator-Universitaet Duisburg, FB 6 - Institut fuer Synthesechemie, Duisburg, Germany

Abstract: The dimethylpalladium(II) PdMe₂(tacn) complex supported with 1,4,7-triazacyclononane (tacn), obtained in situ via a reaction etween PdMe₂(tmeda) and tacn reacts with methyl or ethyl iodide (RI) to form the most stable trialkyl palladium(IV) complexes [PdMe₂R(tacn)]I.

Language: English

DOI: 10.1070/MC2002v012n01ABEH001530