Yu. A. Serguchev, L. F. Lourie, M. V. Ponomarenko, “Difluorination ability of F-TEDA-BF<sub>4</sub> in the transannular cyclization of bicyclo[3.3.1]nonane dienes in monoglyme”, Mendeleev Commun., 2002, Volume 12, Issue 1,Pages <nobr>23

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Difluorination ability of F-TEDA-BF₄ in the transannular cyclization of bicyclo[3.3.1]nonane dienes in monoglyme

Yu. A. Serguchev, L. F. Lourie, M. V. Ponomarenko

Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

Abstract: The interaction of 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (F-TEDA-BF₄) with 3,7-bismethylenebicyclo[3.3.1]nonane and its derivatives in monoglyme results in the transannular cyclization of the dienes to form 1-fluoro-3-fluoroalkyladamantanes.

Language: English

DOI: 10.1070/MC2002v012n01ABEH001531