S. S. Hladyi, M. K. Starchevsky, Yu. A. Pazdersky, M. N. Vargaftik, I. I. Moiseev, “Oxidative and anaerobic reactions of benzyl alcohol catalysed by a Pd-561 giant cluster”, Mendeleev Commun., 2002, Volume 12, Issue 2,Pages <nobr>45

This article is cited in 14 papers

Oxidative and anaerobic reactions of benzyl alcohol catalysed by a Pd-561 giant cluster

S. S. Hladyi^a, M. K. Starchevsky^a, Yu. A. Pazdersky^a, M. N. Vargaftik^b, I. I. Moiseev^b

^a ''Sintez'' Research Institute, Borislav, Ukraine
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The unusual redox disproportionation of benzyl alcohol to benzaldehyde and toluene catalysed by the Pd₅₆₁phen₆₀(OAc)₁₈₀ giant cluster under anaerobic conditions was found, whereas in an O₂ atmosphere the Pd giant cluster catalyses benzyl alcohol oxidation to benzaldehyde and inhibits its further oxidation.

Language: English

DOI: 10.1070/MC2002v012n02ABEH001568