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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2002 Volume 12, Issue 3, Pages 110–111 (Mi mendc4117)

This article is cited in 5 papers

Prop-2-yn-1-als and 1-phenylprop-2-yn-1-one in the chalcogen Baylis–Hillman reaction

A. S. Medvedeva, M. M. Demina, P. S. Novopashin, G. I. Sarapulova, A. V. Afonin

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: 2-(Z,E-Chloromethylidene)-3-hydroxy-1-phenyl-5-organylpent-4-yn-1-ones were prepared by tandem α-hydroxyethynylation/β-chlorination of 1-phenylprop-2-yn-1-one mediated by TiCl4 and Me2S in the chalcogen Baylis–Hillman reaction.

Language: English

DOI: 10.1070/MC2002v012n03ABEH001553



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