I. S. Orlov, A. A. Moiseeva, K. P. Butin, L. R. Sita, M. P. Egorov, O. M. Nefedov, “Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation”, Mendeleev Commun., 2002, Volume 12, Issue 4,Pages <nobr>125

This article is cited in 9 papers

Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation

I. S. Orlov^a, A. A. Moiseeva^b, K. P. Butin^b, L. R. Sita^c, M. P. Egorov^a, O. M. Nefedov^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c Department of Chemistry and Biochemistry, University of Maryland, Maryland, USA

Abstract: The radical anion of di(2,6-diethylphenyl)stannylene (Ar₂Sn) has been generated by the electrochemical reduction of cyclotristannane cyclo-(Ar₂Sn)₃, and the electrochemical oxidation of cyclo-(Ar₂Sn)₃ resulted in Sn–Sn bond cleavage with the formation of the radical cation of tristannane.

Language: English

DOI: 10.1070/MC2002v012n04ABEH001601