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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2001 Volume 11, Issue 1, Pages 14–15 (Mi mendc4193)

This article is cited in 7 papers

Synthesis of closo-monocarbon carborane-substituted natural porphyrins

V. A. Ol'shevskayaa, R. P. Evstigneevab, V. N. Luzginab, M. A. Gyul'malievab, P. V. Petrovskiia, J. H. Morrisc, L. I. Zakharkina

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
c Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK

Abstract: Previously unknown 1,3,5,8-tetramethyl-6,7-di[2′-(closo-monocarbon carborane-1″-yl caesium)methoxycarbonylethyl]porphyrin and 1,3,5,8-tetramethyl-2,4-divinyl-6,7-di[2′-(closo-monocarbon carborane-1″-yl caesium)methoxycarbonylethyl]porphyrin were synthesised in the reactions of deuteroporphyrin IX and protoporphyrin IX, respectively, with (1-hydroxymethyl-closo-monocarbon carborane)caesium.

Language: English

DOI: 10.1070/MC2001v011n01ABEH001383



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