S. V. Chapyshev, M. S. Platz, “Selective reduction of the azido groups of 2,4,6-triazidopyridines”, Mendeleev Commun., 2001, Volume 11, Issue 2,Pages <nobr>56

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Selective reduction of the azido groups of 2,4,6-triazidopyridines

S. V. Chapyshev^a, M. S. Platz^b

^a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b Department of Chemistry, Ohio State University, Columbus, OH, USA

Abstract: Upon treatment with SnCl₂ in methanol at room temperature, 2,4,6-triazidopyridines undergo selective reduction of the γ-azido groups to give the corresponding 4-amino-2,6-diazidopyridines in high yields.

Language: English

DOI: 10.1070/MC2001v011n02ABEH001412