A. M. Vasil'tsov, A. B. Zaitsev, E. Yu. Schmidt, A. I. Mikhaleva, A. V. Afonin, “Unexpected formation of 1-vinyl-2-[2′-(6′-methylpyridyl)]pyrrole from dimethylglyoxime and acetylene in the Trofimov reaction”, Mendeleev Commun., 2001, Volume 11, Issue 2,Pages <nobr>74

This article is cited in 11 papers

Unexpected formation of 1-vinyl-2-[2′-(6′-methylpyridyl)]pyrrole from dimethylglyoxime and acetylene in the Trofimov reaction

A. M. Vasil'tsov, A. B. Zaitsev, E. Yu. Schmidt, A. I. Mikhaleva, A. V. Afonin

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: Dimethylglyoxime reacts with acetylene under pressure in the KOH–DMSO system to give 1-vinyl-2-[2′-(6′-methylpyridyl)]- pyrrole along with the expected products of the Trofimov reaction (O-vinyloxime, pyrrole and dipyrrole).

Language: English

DOI: 10.1070/MC2001v011n02ABEH001405