S. V. Chapyshev, P. R. Serwinski, “A new nitrene to carbene rearrangement upon photolysis of 4-amino-2,6-diazido-3,6-dichloropyridine”, Mendeleev Commun., 2001, Volume 11, Issue 3,Pages <nobr>92

This article is cited in 9 papers

A new nitrene to carbene rearrangement upon photolysis of 4-amino-2,6-diazido-3,6-dichloropyridine

S. V. Chapyshev^a, P. R. Serwinski^b

^a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b Department of Chemistry, University of Massachusetts, Amherst, USA

Abstract: A novel rearrangement of quintet 2,6-dinitrenopyridine to 3-nitreno-1,2-diazacycloheptatrienylidene was discovered by EPR spectroscopy during the photolysis of 4-amino-2,6-diazido-3,5-dichloropyridine in a cryogenic matrix at 77 K.

Language: English

DOI: 10.1070/MC2001v011n03ABEH001439