N. Sh. Pirkuliev, V. K. Brel, N. G. Akhmedov, N. S. Zefirov, P. J. Stang, “Xenon difluoride–trimethylsilyl isocyanate–triflic acid as a new system for the amination of aromatic compounds”, Mendeleev Commun., 2001, Volume 11, Issue 5,Pages <nobr>172–173</nobr>

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Mendeleev Commun., 2001 Volume 11, Issue 5, Pages 172–173 (Mi mendc4278)

This article is cited in 5 papers

Xenon difluoride–trimethylsilyl isocyanate–triflic acid as a new system for the amination of aromatic compounds

N. Sh. Pirkuliev^a, V. K. Brel^a, N. G. Akhmedov^b, N. S. Zefirov^b, P. J. Stang^c

^a Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c Department of Chemistry, University of Utah, Salt Lake City, Utah, USA

Abstract: In the title system, OCNXeOSO₂CF₃ is formed, which readily oxidises iodobenzene to PhI⁺–NCO –OTf. The direct amination of aromatic substrates is possible with the use of XeF₂–Me₃SiNCO–CF₃SO₃H.

Language: English

DOI: 10.1070/MC2001v011n05ABEH001514

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