D. S. Chekmarev, A. V. Maskaev, G. V. Zatonsky, M. I. Lazareva, R. Caple, W. A. Smit, “Selectivity of the Lewis acid-induced transformations of polyfunctional compounds containing a 4,6-dialkoxy-7-(arylthio)heptene moiety”, Mendeleev Commun., 2001, Volume 11, Issue 5,Pages <nobr>176

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Selectivity of the Lewis acid-induced transformations of polyfunctional compounds containing a 4,6-dialkoxy-7-(arylthio)heptene moiety

D. S. Chekmarev^a, A. V. Maskaev^a, G. V. Zatonsky^b, M. I. Lazareva^a, R. Caple^c, W. A. Smit^b

^a Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c Department of Chemistry, University of Minnesota Duluth, Duluth, Minnesota, USA

Abstract: The interaction of the title adducts with Lewis acids may proceed as an attack at either β-alkoxy or δ-alkoxy group to the arylthio substituent leading to the formation of substituted cyclohexane or 1,3-diene derivatives, respectively.

Language: English

DOI: 10.1070/MC2001v011n05ABEH001513