V. Yu. Kotov, Yu. G. Gorbunova, S. A. Kostina, G. K. Kadorkina, V. R. Kostyanovsky, R. G. Kostyanovsky, “Outer-sphere association of hexacyanoferrate and nitrogen betaine anions”, Mendeleev Commun., 2001, Volume 11, Issue 5,Pages <nobr>181–182</nobr>

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Mendeleev Commun., 2001 Volume 11, Issue 5, Pages 181–182 (Mi mendc4282)

This article is cited in 3 papers

Outer-sphere association of hexacyanoferrate and nitrogen betaine anions

V. Yu. Kotov^a, Yu. G. Gorbunova^b, S. A. Kostina^a, G. K. Kadorkina^c, V. R. Kostyanovsky^c, R. G. Kostyanovsky^c

^a Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^b Russian Research Centre 'Research Institute of Organic Intermediates and Dyes', Moscow, Russian Federation
^c N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The electronic spectrum of an aqueous solution of an equimolar mixture of nitrogen betaine (pK₁ = 1.72, pK₂ = 3.62) and hexacyanoferrate anions exhibited a charge-transfer band at 26100 cm^–1, which is indicative of the outer-sphere association of these ions.

Language: English

DOI: 10.1070/MC2001v011n05ABEH001464

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