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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2001 Volume 11, Issue 5, Pages 196–197 (Mi mendc4290)

This article is cited in 13 papers

An alternative reaction of ortho-(N-benzylidene)aminophenol with chlorophosphites: formation of 2-(2’-alkoxy)-2-oxo-3-phenyl-5,6-benzo-1,4,2-oxazaphosphorinanes

M. N. Dimukhametov, E. V. Bayandina, E. Yu. Davydova, A. B. Dobrynin, A. T. Gubaidullin, I. A. Litvinov, V. A. Alfonsov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The reactions of o-(N-benzylidene)aminophenol with ethylene chlorophosphite and diethyl chlorophosphite in CHCl3 in the absence of an external acceptor of HCl result in the formation of diastereomeric 2-(2’-alkoxy)-2-oxo-3-phenyl-5,6-benzo-1,4,2-oxazaphosphorinanes different in the configurations of phosphorus atoms.

Language: English

DOI: 10.1070/MC2001v011n05ABEH001478



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