Ya. V. Demyanov, M. I. Rakhmanova, I. Yu. Bagryanskaya, A. V. Artem'ev, “Cu4I4-cubane cluster based on tris(p-anisyl)arsine: Synthesis, crystal structure and photophysical properties”, Mendeleev Commun., 2023, Volume 33, Issue 4,Pages 484

This article is cited in 3 papers

Communications

Cu₄I₄-cubane cluster based on tris(p-anisyl)arsine: Synthesis, crystal structure and photophysical properties

Ya. V. Demyanov^a, M. I. Rakhmanova^a, I. Yu. Bagryanskaya^b, A. V. Artem'ev^a

^a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: A new cubane cluster [Cu₄I₄(AsAn₃)₄] was synthesized in 82% yield by the reaction of tris(p-anisyl)arsine (AsAn₃) with CuI. At ambient temperature, this cluster exhibits bright yellow-green phosphorescence (λ_max = 546 nm) with the quantum yield of 35% and 4.1 μs decay time.

Keywords: copper(i) complexes, tris(p-anisyl)arsine, cubane-like clusters, photoluminescence, crystal structure.

Language: English

DOI: 10.1016/j.mencom.2023.06.014

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